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Thankfully, there is no shortage of ways to get more PokéBalls in Pokémon GO — though if you’re looking to stockpile them, you’ll have to do a bit of grinding.
Probably the easiest way to obtain more PokéBalls is to visit PokéStops. These are various landmarks that are located around your neighborhood that are indicated by pins on the game’s map. When you walk near one, the pin will sprout a spinning PokéStop icon above it, indicating you can collect items from it.
Source: https://www.distractify.com/p/how-to-get-more-pokeballs-pokemon-go
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